Advanced biodegradable plastics run rings around their predecessors – Japan

Advanced biodegradable plastics run rings around their predecessors – Japan

Posted on November 1, 2024 by DrRossH in Plastic Waste News

Source: Advanced biodegradable plastics run rings around their predecessors

Plastics and polymers need to achieve both desirable performance in terms of durability and strength, as well as triggerable degradation capability to enable their breakdown into useful components for reuse. At present, there is a tradeoff between these factors; i.e., increased toughness makes the polymer more difficult to degrade. The researchers have used movable crosslinks to resolve this problem.

The movable crosslinks are ring-like cyclodextrins, which are threaded on one polymer strand and attached to another, endowing the resulting plastics with increased toughness and durability. Cyclodextrins are nontoxic, biodegradable, and widely available, making them attractive as a polymer component.

“Our polymer design using movable cyclodextrin crosslinks increased polymer toughness by over eight times,” says lead author of the study Jiaxiong Liu. “Stiffness, ductility, fracture stress, and fracture strain all improved because the cyclodextrin groups effectively dispersed local stress.”

The cyclodextrin crosslinks also facilitated degradation of the polymers during subsequent enzymatic treatment because their bulky structure increased the free volume in the polymer network, which improved access of the enzyme to the target cleavage sites on the polymer chains.

“The polymers were readily degraded by Novozym 435, an enzyme that specifically attacks the ester bonds of the polymer backbone,” explains Yoshinori Takashima, senior author. “The presence of the bulky cyclodextrin crosslink groups decreased entanglement and aggregation of the , which facilitated the access of the  to the ester bonds for cleavage.” As a result, biodegradability was improved by twenty times compared with that of the polymer without  groups.